Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds.
نویسندگان
چکیده
Flavins and related molecules catalyze organic Baeyer-Villiger reactions. Combined experimental and DFT studies indicate that these molecules also catalyze the insertion of oxygen into metal-carbon bonds through a Baeyer-Villiger-like transition state.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 134 31 شماره
صفحات -
تاریخ انتشار 2012